\(n_{H_2}=\dfrac{8,064}{22,4}=0,36\left(mol\right)\)
PTHH: 2R + 2nHCl --> 2RCln + nH2
\(\dfrac{0,72}{n}\)<-----------------0,36
\(m_{tăng}=m_R-m_{H_2}=\dfrac{0,72}{n}.M_R-0,36.2=19,44\left(g\right)\)
=> \(M_R=28n\left(g/mol\right)\)
Xét n = 2 thỏa mãn => MR = 56 (g/mol)
=> R là Fe
\(n_{Fe}=0,36\left(mol\right)\)
\(n_{CO\left(bđ\right)}=\dfrac{16,128}{22,4}=0,72\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=0,21.2=0,42\left(mol\right)\); \(n_{BaCO_3}=\dfrac{59,1}{197}=0,3\left(mol\right)\)
TH1: Kết tủa không bị hòa tan
PTHH: Ba(OH)2 + CO2 --> BaCO3 + H2O
0,3<----0,3
FexOy + yCO --to--> xFe + yCO2
\(\dfrac{0,3x}{y}\)<-0,3
=> \(\dfrac{0,3x}{y}=0,36\Rightarrow\dfrac{x}{y}=\dfrac{6}{5}\left(L\right)\)
TH2: Kết tủa bị hòa tan 1 phần
PTHH: Ba(OH)2 + CO2 --> BaCO3 + H2O
0,42---->0,42---->0,42
BaCO3 + CO2 + H2O --> Ba(HCO3)2
0,12-->0,12
=> \(n_{CO_2}=0,42+0,12=0,54\left(mol\right)\)
PTHH: FexOy + yCO --to--> xFe + yCO2
\(\dfrac{0,54x}{y}\)<-0,54
=> \(\dfrac{0,54x}{y}=0,36\Rightarrow\dfrac{x}{y}=\dfrac{2}{3}\)
=> CTHH: Fe2O3
\(n_{Fe_2O_3}=\dfrac{1}{2}.n_{Fe}=0,18\left(mol\right)\Rightarrow m=0,18.160=28,8\left(g\right)\)
CTHH của oxit: `R_xO_y`
\(n_{CO\left(ban,đầu\right)}=\dfrac{16,128}{22,4}=0,72\left(mol\right)\)
\(n_{H_2}=\dfrac{8,064}{22,4}=0,36\left(mol\right)\)
Ta có: \(m_{tăng}=m_{KL}-m_{H_2}=19,44\left(g\right)\)
\(\rightarrow m_{KL}=19,44+0,36.2=20,16\left(g\right)\)
PTHH: \(2R+2nHCl\rightarrow2RCl_n+nH_2\)
\(\dfrac{0,72}{n}\)<----------------------0,36
\(\rightarrow M_R=\dfrac{20,16}{\dfrac{0,72}{n}}=28n\left(g\text{/}mol\right)\)
Với `n = 2 -> M_R = 56` $(g/mol)$
=> R là Fe
\(n_{Fe}=\dfrac{20,16}{56}=0,36\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=0,21.2=0,42\left(mol\right)\)
\(n_{BaCO_3}=\dfrac{59,1}{197}=0,3\left(mol\right)\\ \xrightarrow[]{\text{BTNT Ba}}n_{Ba\left(HCO_3\right)_2}=0,42-0,3=0,12\left(mol\right)\\ \xrightarrow[]{\text{BTNT C}}n_{CO_2}=0,12.2+0,3=0,54\left(mol\right)\)
So sánh: `0,54 < 0,72 => CO` dư
PT rút gọn: \(CO+O\rightarrow CO_2\)
0,54<-0,54
CTHH: `Fe_xO_y`
`-> x : y = 0,36 : 0,54 = 2 : 3`
CTHH: `Fe_2O_3`
\(n_{H_2}=\dfrac{8,064}{22,4}=0,36\left(mol\right)\)
PTHH: 2R + 2nHCl --> 2RCln + nH2
\(\dfrac{0,72}{n}\)<-----------------0,36
\(m_{tăng}=m_R-m_{H_2}=\dfrac{0,72}{n}.M_R-0,36.2=19,44\left(g\right)\)
=> \(M_R=28n\left(g/mol\right)\)
Xét n = 2 thỏa mãn => MR = 56 (g/mol)
=> R là Fe
\(n_{Fe}=0,36\left(mol\right)\)
\(n_{CO\left(bđ\right)}=\dfrac{16,128}{22,4}=0,72\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=0,21.2=0,42\left(mol\right)\); \(n_{BaCO_3}=\dfrac{59,1}{197}=0,3\left(mol\right)\)
TH1: Kết tủa không bị hòa tan
PTHH: Ba(OH)2 + CO2 --> BaCO3 + H2O
0,3<----0,3
FexOy + yCO --to--> xFe + yCO2
\(\dfrac{0,3x}{y}\)<-0,3
=> \(\dfrac{0,3x}{y}=0,36\Rightarrow\dfrac{x}{y}=\dfrac{6}{5}\left(L\right)\)
TH2: Kết tủa bị hòa tan 1 phần
PTHH: Ba(OH)2 + CO2 --> BaCO3 + H2O
0,42---->0,42---->0,42
BaCO3 + CO2 + H2O --> Ba(HCO3)2
0,12-->0,12
=> \(n_{CO_2}=0,42+0,12=0,54\left(mol\right)\)
PTHH: FexOy + yCO --to--> xFe + yCO2
\(\dfrac{0,54x}{y}\)<-0,54
=> \(\dfrac{0,54x}{y}=0,36\Rightarrow\dfrac{x}{y}=\dfrac{2}{3}\)
=> CTHH: Fe2O3