$n_{CO_2} = \dfrac{6,72}{22,4} = 0,3(mol) > n_{CaCO_3} = \dfrac{12}{100} = 0,12(mol)$
Do đó, có tạo muối axit
CO2 + Ca(OH)2 → CaCO3 + H2O
0,12......0,12.............0,12..................(mol)
2CO2 + Ca(OH)2 → Ca(HCO3)2
0,18..........0,09................................(mol)
$n_{Ca(OH)_2} = 0,12 + 0,09 = 0,21(mol)$
$C_{M_{Ca(OH)_2}} = \dfrac{0,21}{0,1} = 2,1M$
\(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(n_{CaCO_3}=\dfrac{12}{100}=0,12\left(mol\right)\)
Vì tạo kết tủa nên CO2 phải phản ứng hết
=>Bảo toàn nguyên tố C : \(n_{Ca\left(HCO_3\right)_2}.2+n_{CaCO_3}=n_{CO_2}\)
=> \(n_{Ca\left(HCO_3\right)_2}=0,09\left(mol\right)\)
Bảo toàn nguyên tố Ca
=> \(n_{Ca\left(HCO_3\right)_2}+n_{CaCO_3}=n_{Ca\left(OH\right)_2}\)
=> \(n_{Ca\left(OH\right)_3}=0,21\left(mol\right)\)
=> \(CM_{\text{}Ca\left(OH\right)_2}=\dfrac{0,21}{0,1}=2,1M\)
nCaCO3=0,12(mol)
nCO2=0,3(mol)
PTHH: Ca(OH)2 + CO2 -> CaCO3 + H2O (1)
x___________x________x(mol)
CaCO3 + CO2 + H2O -> Ca(HCO3)2 (2)
y_________y_____________y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}x-y=0,12\\x+y=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,21\\y=0,09\end{matrix}\right.\)
=> CMddCa(OH)2= 0,21/0,1=2,1(M)