\(n_{Zn}=\dfrac{1,95}{65}=0,03\left(mol\right)\\
m_{H_2SO_4}=\dfrac{22,05.20}{100}=4,41\left(g\right)\\
n_{H_2SO_4}=\dfrac{4,41}{98}=0,045\left(mol\right)\\
pthh:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
\(LTL:\dfrac{0,03}{1}< \dfrac{0,045}{1}\)
=> H2SO4 dư
\(n_{H_2SO_4\left(p\text{ư}\right)}=n_{ZnSO_4}=n_{H_2}=n_{Zn}=0,03\left(mol\right)\\
m_{H_2SO_4\left(d\right)}=\left(0,045-0,03\right).98=1,47\left(g\right)\\
m_{\text{dd}}=1,95+22,05-\left(0,03.2\right)=23,94\left(g\right)\\
C\%_{ZnCl_2}=\dfrac{0,03.136}{23,94}.100\%=17\%\)
\(a,n_{Zn}=\dfrac{1,95}{65}=0,03\left(mol\right)\\ n_{H_2SO_4}=\dfrac{22,05}{98}=0,225\left(mol\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
bđ 0,03 0,225
pư 0,03 0,03
spư 0 0,195 0,03 0,03
\(b,m_{H_2SO_4\left(dư\right)}=0,195.98=19,11\left(g\right)\\ c,m_{dd}=1,95+22,05-0,03.2=23,94\left(g\right)\\ C\%_{ZnSO_4}=\dfrac{0,03.161}{23,94}.100\%=20,18\%\)