2KClO3 -> 2KCl + 3O2
a.nO2 = 0.28125mol
=> nKClO3 = 0.1875mol
=> mKClO3 = 22.97g
b.nKCl = nKClO3 = 0.1875mol
=> mKCl = 13.97g
$a)PTHH:2KClO_3\xrightarrow{t^o}2KCl+3O_2$
$n_{O_2}=\dfrac{9}{32}=0,28125(mol)$
$\Rightarrow n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,1875(mol)$
$\Rightarrow m_{KClO_3}=0,1875.122,5=22,96875(g)$
$b)$ Theo PT: $n_{KCl}=n_{KClO_3}=0,1875(mol)$
$\Rightarrow m_{KCl}=0,1875.74,5=13,96875(g)$