Gọi số mol CuO, FexOy là a, b
=> 80a + b(56x+16y) = 2,4 (1)
\(n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
a---------------->a
FexOy + yH2 --to--> xFe + yH2O
b------------------->bx
Fe + 2HCl --> FeCl2 + H2
bx--------------->bx
=> bx = 0,02
Có 64a + 56bx = 1,76
=> a = 0,01 => b = 0,01 => x = 2
(1) => 56x + 16y = 160 => y = 3
=> CTHH: Fe2O3
\(pthh:\)
\(CuO+H_2\overset{t^o}{--->}Cu+H_2O\left(1\right)\)
\(Fe_xO_y+yH_2\overset{t^o}{--->}xFe+yH_2O\left(2\right)\)
\(Fe+2HCl--->FeCl_2+H_2\uparrow\left(3\right)\)
Ta có: \(n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)
Theo pt(3): \(n_{Fe}=n_{H_2}=0,02\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,02.56=1,12\left(g\right)\)
\(\Rightarrow m_{Cu}=1,76-1,12=0,64\left(g\right)\)
\(\Rightarrow n_{Cu}=\dfrac{0,64}{64}=0,01\left(mol\right)\)
Theo pt(1): \(n_{CuO}=n_{Cu}=0,01\left(mol\right)\)
\(\Rightarrow m_{CuO}=0,01.80=0,8\left(g\right)\)
\(\Rightarrow m_{Fe_xO_y}=2,4-0,8=1,6\left(g\right)\)
Theo pt(2): \(n_{Fe_xO_y}=\dfrac{1}{x}.n_{Fe}=\dfrac{1}{x}.0,02=\dfrac{0,02}{x}\left(mol\right)\)
\(\Rightarrow m_{Fe_xO_y}=\dfrac{0,02}{x}.\left(56x+16y\right)=1,12+\dfrac{0,32y}{x}\left(g\right)\)
\(\Rightarrow1,12+\dfrac{0,32y}{x}=1,6\)
\(\Leftrightarrow\dfrac{x}{y}=\dfrac{2}{3}\)
Vậy CTHH của oxit sắt là: Fe2O3