Dd B chứa NaOH.
PT: \(NaOH+HCl\rightarrow NaCl+H_2O\)
Ta có: \(n_{NaCl}=\dfrac{4,68}{58,5}=0,08\left(mol\right)\)
Theo PT: \(n_{NaOH\left(80\left(g\right)dd\right)}=n_{NaCl}=0,08\left(mol\right)\)
\(\Rightarrow n_{NaOH\left(200\left(g\right)dd\right)}=\dfrac{0,08.200}{80}=0,2\left(mol\right)\)
PT: \(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(\left\{{}\begin{matrix}23n_{Na}+62n_{Na_2O}=5,4\\n_{Na}+2n_{Na_2O}=0,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{Na}=0,1\left(mol\right)\\n_{Na_2O}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=\dfrac{1}{2}n_{Na}=0,05\left(mol\right)\)
Ta có: m dd B = mA + mH2O - mH2
⇒ 200 = 5,4 + mH2O - 0,05.2
⇒ mH2O = 194,7 (g)