a. PTHH:
\(BaO+2HCl--->BaCl_2+H_2O\left(1\right)\)
\(BaCO_3+2HCl--->BaCl_2+CO_2\uparrow+H_2O\left(2\right)\)
Ta có: \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT(2): \(n_{BaCO_3}=n_{CO_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{BaCO_3}=0,2.197=39,4\left(g\right)\)
\(\Rightarrow\%_{m_{BaCO_3}}=\dfrac{39,4}{54,7}.100\%=72,03\%\)
\(\%_{m_{BaO}}=100\%-72,03\%=27,97\%\)
b. Ta có: \(m_{BaO}=54,7-39,4=15,3\left(g\right)\)
\(\Rightarrow n_{BaO}=\dfrac{15,3}{153}=0,1\left(mol\right)\)
\(\Rightarrow n_A=0,1+0,2=0,3\left(mol\right)\)
Theo PT(1,2): \(n_{HCl}=2.n_A=2.0,3=0,6\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\)
Ta có: \(C_{\%_{HCl}}=\dfrac{21,9}{m_{dd_{HCl}}}.100\%=20\%\)
\(\Rightarrow m_{dd_{HCl}}=109,5\left(g\right)\)
\(n_{CO2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
a) Pt : \(BaO+2HCl\rightarrow BaCl_2+H_2O|\)
1 2 1 1
0,1 0,2
\(BaCO_3+2HCl\rightarrow BaCl_2+CO_2+H_2O|\)
1 2 1 1 1
0,2 0,4 0,2
\(n_{BaCO3}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(m_{BaCO3}=0,2.197=39,4\left(g\right)\)
\(m_{BaO}=54,7-39,4=15,3\left(g\right)\)
0/0BaO = \(\dfrac{15,3.100}{54,7}=27,97\)0/0
0/0BaCO3 = \(\dfrac{39,4.100}{54,7}=72,03\)0/0
b) Có : \(m_{BaO}=15,3\left(g\right)\)
\(n_{BaO}=\dfrac{15,3}{153}=0,1\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,2+0,4=0,6\left(mol\right)\)
\(m_{HCl}=0,6.36,5=21,9\left(g\right)\)
\(m_{ddHCl}=\dfrac{21,9.100}{20}=109,5\left(g\right)\)
Chúc bạn học tốt
nCO2= 4,48 / 22.4= 0,2 ( mol)
a, BaO + 2HCl -> BaCl2 + H2O (1)
BaCO3 + 2HCl-> BaCl2 + H2O + CO2 (2)
0,2 <- 0,2 (mol)
Theo pt (2) ta có nBaCO3= 0,2 => mBaCO3= 0,2 x 197= 39,4 (g)
=> mBaO= 54,7- 39,4= 15.3 (g)
->% BaCO3= ( 39,4 : 54,7)x 100%= 72%
->% BaO= 100%-72% = 28%
