\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(0.2........0.6.........0.2.........0.3\)
\(V_{dd_{HCl}}=\dfrac{0.6}{2}=0.3\left(l\right)\)
\(m_{AlCl_3}=0.2\cdot133.5=26.7\left(g\right)\)
\(V_{H_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(n_{Fe_2O_3}=\dfrac{32}{160}=0.2\left(mol\right)\)
\(Fe_2O_3+3H_2\underrightarrow{^{t^0}}2Fe+3H_2O\)
\(1..............3\)
\(0.2............0.3\)
\(LTL:\dfrac{0.2}{1}>\dfrac{0.3}{3}\Rightarrow Fedư\)
\(m_{Cr}=m_{Fe_2O_3\left(dư\right)}+m_{Fe}=\left(0.2-0.1\right)\cdot160+0.2\cdot56=27.2\left(g\right)\)
a) 2Al + 6HCl $\to$ 2AlCl3 + 3H2
b)
n Al = 5,4/27 = 0,2(mol)
Theo PTHH : n HCl = 3n Al = 0,6(mol)
=> V = 0,6/2 = 0,3(lít)
n AlCl3 = n Al = 0,2(mol)
=> m = 0,2.133,5 = 26,7(gam)
c) n H2 = 1/2 n HCl = 0,3(mol)
n Fe2O3 = 32/160 = 0,2(mol)
$Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O$
Ta thấy : n Fe2O3 /1 = 0,2 > n H2 /3 = 0,1 => Fe2O3 dư
Theo PTHH : n H2O = n H2 = 0,3(mol)
Bảo toàn khối lượng :
m Fe2O3 + m H2 = m chất rắn + m H2O
=> m chất rắn = 32 + 0,3.2 - 0,3.18 = 27,2 gam