\(n_{SO_2}=\dfrac{7.84}{22.4}=0.35\left(mol\right)\)
\(n_{NaOH}=0.3\cdot2=0.6\left(mol\right)\)
\(\dfrac{n_{NaOH}}{n_{SO_2}}=\dfrac{0.6}{0.35}=1.7\)
=> Tạo ra 2 muối
\(n_{Na_2SO_3}=a\left(mol\right),n_{NaHSO_3}=b\left(mol\right)\)
\(2NaOH+SO_2\rightarrow Na_2SO_3+H_2O\)
\(NaOH+SO_2\rightarrow NaHSO_3\)
\(BTNa:\) \(2a+b=0.6\)
\(BTS:a+b=0.35\)
\(a=0.25,b=0.1\)
\(m_M=0.25\cdot127+0.1\cdot104=42.4\left(g\right)\)
n NaOH = 0,3.2 = 0,6(mol)
n SO2 = 7,84/22,4 = 0,35(mol)
Ta có :
1 < n NaOH / n SO2 = 0,6/0,35 = 1,7 < 2 nên phản ứng sinh ra : Na2SO3(a mol) , NaHSO3(b mol)
Bảo toàn nguyên tố Na,S :
n NaOH = 2a + b = 0,6(mol)
n SO2 = a + b = 0,35(mol)
=> a = 0,25 ; b = 0,1
=> m muối = 0,25.126 + 0,1.104 = 41,9 gam