\(\dfrac{n_{OH^{^{ }-}}}{n_{CO_2}}=\dfrac{0,125.2}{\dfrac{3,36}{22,4}}=1,67\Rightarrow Tạo.2.muối\\ Ba\left(OH\right)_2+CO_2->BaCO_3+H_2O\\ BaCO_3+CO_2+H_2O->Ba\left(HCO_3\right)_2\\ n_{BaCO_3max}=0,125mol=n_{CO_2\left(1\right)}\\ n_{Ba\left(HCO_3\right)_2}=0,15-0,125=0,025mol\\ C_{M\left(Ba\left(HCO_3\right)_2\right)}=\dfrac{0,025}{0,125}=0,2M\)
Tham khảo:
nCO2=0,15 mol, nBa(OH)2=0,125 mol
1<nOH-/nCO2=0,25/0,15=1,67<2 => Tạo 2 muối
BaCO3: x
Ba(HCO3)2: y
x+y=nBa2+=0,125
x+2y=nC=0,15
=>x=0,1; y=0,025
CM Ba(HCO3)2=0,025/0,125=0,2M
\(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=0,125\cdot1=0,125\left(mol\right)\)
\(T=\dfrac{n_{Ba\left(OH\right)_2}}{n_{CO_2}}=\dfrac{0,125}{0,15}=\dfrac{5}{6}\Rightarrow\dfrac{1}{2}< T< 1\)
⇒ Phản ứng tạo ra 2 muối \(Ba\left(HCO_3\right)_2\) và \(BaCO_3\downarrow\).
Gọi số mol \(\left\{{}\begin{matrix}Ba\left(HCO_3\right)_2:x\\BaCO_3:y\end{matrix}\right.\left(mol\right).ĐK:x;y>0\)
PTPƯ:
\(Ba\left(OH\right)_2+2CO_2\rightarrow Ba\left(HCO_3\right)_2\)
x ← 2x ← x
\(Ba\left(OH\right)_2+CO_2\rightarrow BaCO_3\downarrow+H_2O\)
y ← y ← y
Ta có hpt:
\(\left\{{}\begin{matrix}2x+y=0,15\\x+y=0,125\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,025\\y=0,1\end{matrix}\right.\)
Nồng độ chất tan:
\(C_M\left[\left(BaHCO_3\right)_2\right]=\dfrac{0,025}{0,125}=0,2\left(M\right)\)
