a)
Gọi số mol Cu, Mg là a, b (mol)
=>64a + 24b = 17,6 (1)
PTHH: \(2Cu+O_2\underrightarrow{t^o}2CuO\)
a-->0,5a-->a
\(2Mg+O_2\underrightarrow{t^o}2MgO\)
b--->0,5b--->b
=> 80a + 40b = 24 (2)
(1)(2) => a = 0,2 (mol); b = 0,2 (mol)
\(\left\{{}\begin{matrix}m_{Cu}=0,2.64=12,8\left(g\right)\\m_{Mg}=0,2.24=4,8\left(g\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{12,8}{17,6}.100\%=72,7\%\\\%m_{Mg}=\dfrac{4,8}{17,6}.100\%=27,3\%\end{matrix}\right.\)
b)
C1:
Theo ĐLBTKL: mKL + \(m_{O_2}\) = moxit
=> \(m_{O_2}=24-17,6=6,4\left(g\right)\Rightarrow n_{O_2}=\dfrac{6,4}{32}=0,2\left(mol\right)\Rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\)
C2:
\(n_{O_2}=0,5a+0,5b=0,2\left(mol\right)\Rightarrow\left\{{}\begin{matrix}m_{O_2}=0,2.32=6,4\left(g\right)\\V_{O_2}=0,2.22,4=4,48\left(l\right)\end{matrix}\right.\)
a)
Đặt \(\left\{{}\begin{matrix}n_{Cu}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\left(a,b>0\right)\)
=> 64a + 24b = 17,6 (1)
PTHH:
2Cu + O2 --to--> 2CuO
a--------0,5----------->a
2Mg + O2 --to--> 2MgO
b---------0,5---------->b
=> 80a + 40b = 24 (2)
(1)(2) => \(a=b=0,2\)
=> \(\left\{{}\begin{matrix}m_{Cu}=0,2.64=12,8\left(g\right)\\m_{Mg}=0,2.24=4,8\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{12,8}{17,6}.100\%=72,73\%\\\%m_{Mg}=100\%-72,73\%=27,27\%\end{matrix}\right.\)
b)
Cách 1:
Áp dụng ĐLBTKL:
\(m_{O_2}=24-17,6=6,4\left(g\right)\\ \rightarrow n_{O_2}=\dfrac{6,4}{32}=0,2\left(mol\right)\\ \rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\)
Cách 2:
\(n_{O_2}=0,5.\left(a+b\right)=0,5.\left(0,2+0,2\right)=0,2\left(mol\right)\\ \rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\)