Gọi số mol H2, H2S là a, b (mol)
\(\left\{{}\begin{matrix}a+b=\dfrac{2,24}{22,4}=0,1\\M=\dfrac{2a+34b}{a+b}=9.2=18\left(g/mol\right)\end{matrix}\right.\)
=> a = 0,05 (mol); b = 0,05 (mol)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,05<-------------------0,05
FeS + 2HCl --> FeCl2 + H2S
0,05<---------------------0,05
=> \(\%n_{Fe}=\%n_{FeS}=\dfrac{0,05}{0,05+0,05}.100\%=50\%\)
\(M_{hhkhí}=9.2=18\left(g\text{/}mol\right)\\ n_{hhkhí}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Áp dụng sơ đồ đường chéo, ta có:
\(\dfrac{n_{H_2S}}{n_{H_2}}=\dfrac{V_{H_2S}}{V_{H_2}}=\dfrac{34-18}{18-2}=\dfrac{1}{1}\)
\(\rightarrow n_{H_2S}=n_{H_2}=\dfrac{0,1}{2}=0,05\left(mol\right)\)
PTHH:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,05<-----------------------0,05
\(FeS+2HCl\rightarrow FeCl_2+H_2S\uparrow\)
0,05<-------------------------0,05
\(\rightarrow\left\{{}\begin{matrix}\%n_{Fe}=\dfrac{0,05}{0,05+0,05}.100\%=50\%\\\%n_{FeS}=100\%-50\%=50\%\end{matrix}\right.\)