\(BC=AB\sqrt{2}=a\sqrt{2}\)
\(SB=\sqrt{SC^2+BC^2}=a\sqrt{3}\) ; \(SA=\sqrt{SC^2+AC^2}=a\sqrt{2}\)
\(V_{SBAC}=\dfrac{1}{3}SC.\dfrac{1}{2}AB^2=\dfrac{a^3}{6}\)
\(\dfrac{V_{SCEF}}{V_{SABC}}=\dfrac{SF}{SB}.\dfrac{SE}{SA}=\left(\dfrac{SC}{SB}\right)^2\left(\dfrac{SC}{SA}\right)^2=\left(\dfrac{a}{a\sqrt{3}}\right)^2.\left(\dfrac{a}{a\sqrt{2}}\right)^2=\dfrac{1}{6}\)
\(\Rightarrow V_{SCEF}=\dfrac{1}{6}.\dfrac{a^3}{6}=\dfrac{a^3}{36}\)