\(n_{HCl}=\dfrac{50.18,25}{100.36,5}=0,25(mol)\\ K_2CO_3+2HCl\to 2KCl+H_2O+CO_2\uparrow\\ a,n_{CO_2}=0,125(mol)\\ \Rightarrow V_{CO_2}=0,125.22,4=2,8(l)\\ b,n_{K_2CO_3}=0,125(mol)\\ \Rightarrow m_{K_2CO_3}=0,125.138=17,25(g)\\ c,n_{KCl}=0,25(mol)\\ \Rightarrow C\%_{KCl}=\dfrac{0,25.74,5}{17,25+50-0,125.44}.100\%=30,16\%\)