$a\big)$
$n_{Zn}=\dfrac{3,25}{65}=0,05(mol)$
$Zn+2HCl\to ZnCl_2+H_2$
Theo PT: $n_{ZnCl_2}=n_{Zn}=0,05(mol)$
$\to m_{ZnCl_2}=0,05.136=6,8(g)$
$b\big)$
Theo PT: $n_{HCl}=2n_{Zn}=0,1(mol)$
$\to V_{dd\,HCl}=\dfrac{0,1}{0,5}=0,2(l)=200(ml)$
`Zn + 2HCl -> ZnCl_2 + H_2`
`0,05` `0,1` `0,05` `(mol)`
`n_[Zn]=[3,25]/65=0,05 (mol)`
`a)m_[ZnCl_2]=0,05.136=6,8(g)`
`b)V_[dd HCl]=[0,1]/[0,5]=0,2(M)`