\(n_{NaOH}=0,25.4=1\left(mol\right)\\ n_{Al_2\left(SO_4\right)_3}=2.0,05=0,1\left(mol\right)\\ PTHH:6NaOH+Al_2\left(SO_4\right)_3\rightarrow2Al\left(OH\right)_3+3Na_2SO_4\\ Vì:\dfrac{1}{6}>\dfrac{0,1}{1}\\ \Rightarrow NaOHdư\\ \rightarrow n_{Al\left(OH\right)_3}=2.0,1=0,2\left(mol\right)\\ m_{kt}=m_{Al\left(OH\right)_3}=78.0,2=15,6\left(g\right)\)
\(n_{NaOH}=0.25\cdot4=1\left(mol\right)\)
\(n_{Al_2\left(SO_4\right)_3}=0.05\cdot2=0.1\left(mol\right)\)
\(Al_2\left(SO_4\right)_3+6NaOH\rightarrow2Al\left(OH\right)_3+3Na_2SO_4\)
Lập tỉ lệ :
\(\dfrac{0.1}{1}< \dfrac{1}{6}\) \(\Rightarrow NaOHdư\)
\(n_{NaOH\left(dư\right)}=1-0.6=0.4\left(mol\right)\)
\(n_{Al\left(OH\right)_3}=0.1\cdot2=0.2\left(mol\right)\)
\(NaOH+Al\left(OH\right)_3\rightarrow NaAlO_2+2H_2O\)
\(n_{NaOH}>n_{Al\left(OH\right)_3}\)
=> Kết tủa tan hoàn toàn
\(m_{\downarrow}=0\)
\(n_{NaOH}=1\left(mol\right);n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)\)
Al2(SO4)3 + 6NaOH ⟶ 2Al(OH)3 + 3Na2SO4
0,1...................0,6.................0,2
Al(OH)3 + NaOH ⟶ NaAlO2 + 2H2O
0,2............0,4
=> Sau phản ứng NaOH dư, kết tủa tan hết
=> Khối lượng kết tủa là 0g
