\(CT:ACO_3\)
\(n_{CO_2}=\dfrac{4.4912}{22.4}=0.2005\left(mol\right)\)
\(ACO_3+2HCl\rightarrow ACl_2+CO_2+H_2O\)
\(0.2005.....0.401.....0.2005...0.2005\)
\(M_{ACO_3}=\dfrac{20.05}{0.2005}=100\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow A=100-60=40\)
\(A:Ca\left(Canxi\right)\)
\(m_{CaCl_2}=0.2005\cdot111=22.2555\left(g\right)\)
\(m_{dd}=20.05+100-0.2005\cdot44=111.228\left(g\right)\)
\(C\%_{CaCl_2}=\dfrac{22.2555}{111.228}\cdot100\%=20\%\)