a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
b, Ta có: m dd tăng = mKL - mH2
⇒ mH2 = 16,6 - 15,6 = 1 (g) \(\Rightarrow n_{H_2}=\dfrac{1}{2}=0,5\left(mol\right)\)
Có: 27nAl + 56nFe = 16,6 (1)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=0,5\left(2\right)\)
Từ (1) và (2) ⇒ nAl = nFe = 0,2 (mol)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
c, Theo PT: \(n_{HCl}=2n_{H_2}=1\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{1.36,5}{40\%}=91,25\left(g\right)\)
⇒ m dd sau pư = 91,25 + 15,6 = 106,85 (g)
Theo PT: \(\left\{{}\begin{matrix}n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\\n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{AlCl_3}=\dfrac{0,2.133,5}{106,85}.100\%\approx24,98\%\\C\%_{FeCl_2}=\dfrac{0,2.127}{106,85}.100\%\approx23,77\%\end{matrix}\right.\)
\(2Al+6HCl->2AlCl_3+3H_2\\ Fe+2HCl->FeCl_2+H_2\\ n_{H_2}=\dfrac{16,6-15,6}{2}=0,5mol\\ n_{HCl}=1mol\\ n_{Al}=a;n_{Fe}=b\\ 27a+56b=16,6\\ 3a+2b=1\\ a=b=0,2\\ m_{Al}=0,2.27=5,4g\\ m_{Fe}=0,2.56=11,2g\\ m_{ddsau}=15,6+\dfrac{36,5}{0,4}=106,85g\\ C\%_{AlCl_3}=\dfrac{133,5.0,2}{106,85}.100\%=24,99\%\\ C\%_{FeCl_2}=\dfrac{127.0,2}{106,85}.100\%=23,77\%\)
