a) \(n_{CO_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
\(n_{KOH}=0,75.0,1=0,075\left(mol\right)\)
PTHH: 2KOH + CO2 --> K2CO3 + H2O
0,075--->0,0375---->0,0375
K2CO3 + CO2 + H2O --> 2KHCO3
0,0125<-0,0125----------->0,025
=> \(\left\{{}\begin{matrix}n_{Na_2CO_3}=0,025\left(mol\right)\\n_{NaHCO_3}=0,025\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C_{M\left(Na_2CO_3\right)}=\dfrac{0,025}{0,1}=0,25M\\C_{M\left(NaHCO_3\right)}=\dfrac{0,025}{0,1}=0,25M\end{matrix}\right.\)
b)
PTHH: Na2CO3 + 2HCl --> 2NaCl + CO2 + H2O
0,025----->0,05
NaHCO3 + HCl --> NaCl + CO2 + H2O
0,025----->0,025
=> nHCl = 0,075(mol)
=> \(C_{M\left(HCl\right)}=\dfrac{0,075}{0,2}=0,375M\)