a, \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
\(m_{HCl}=109,5.10\%=10,95\left(g\right)\Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)
PTHH: 2Al + 6HCl → 2AlCl3 + 3H2
Mol: 0,1 0,3 0,1 0,15
Ta có: \(\dfrac{0,1}{2}=\dfrac{0,3}{6}\) ⇒ Al hết, HCl hết
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
b, \(m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\)
c, mdd sau pứ = 2,7 + 109,5 - 0,15.2 = 111,9 (g)
\(C\%_{ddAlCl_3}=\dfrac{13,35.100\%}{111,9}=11,93\%\)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\n_{HCl}=\dfrac{109,5\cdot10\%}{36,5}=0,3\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,1}{2}=\dfrac{0,3}{6}\) \(\Rightarrow\) Al và HCl đều p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{AlCl_3}=0,1\left(mol\right)\\n_{H_2}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{AlCl_3}=0,1\cdot133,5=13,35\left(g\right)\\V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\m_{H_2}=0,15\cdot2=0,3\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Al}+m_{ddHCl}-m_{H_2}=111,9\left(g\right)\)
\(\Rightarrow C\%_{AlCl_3}=\dfrac{13,35}{111,9}\cdot100\%\approx11,93\%\)
