\(a.n_{Fe}=\dfrac{2,8}{56}=0,05\left(mol\right)\\ n_{HCl}=\dfrac{14,6\%.80}{36,5}=0,32\left(mol\right)\\ a.Fe+2HCl\rightarrow FeCl_2+H_2\\ Vì:\dfrac{0,05}{1}< \dfrac{0,32}{2}\\ \Rightarrow HCldư\\ \Rightarrow n_{H_2}=n_{FeCl_2}=n_{Fe}=0,05\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ b.Chất.trong.dd.sau.phản.ứng:FeCl_2,HCl\left(dư\right)\\ m_{ddsau}=2,8+80-0,05.2=82,7\left(g\right)\\ C\%_{ddFeCl_2}=\dfrac{0,05.127}{82,7}.100\approx7,678\%\\n_{HCl\left(dư\right)}=0,32-0,05.2=0,22\left(mol\right)\\ C\%_{ddHCl\left(dư\right)}=\dfrac{0,22.36,5}{82,7}.100\approx9,71\% \)