\(2Al+3CuSO_4\rightarrow Al_2\left(SO_4\right)_3+3Cu\\ Đặt:n_{Al\left(pứ\right)}=x\left(mol\right)\\ m_{tăng}=m_{Cu\left(sinhra\right)}-m_{Al\left(pứ\right)}=\dfrac{3}{2}x.64-x.27=25,69-25\\ \Rightarrow x=0,01\left(mol\right)\\ \Rightarrow n_{CuSO_4\left(dư\right)}=0,2.0,5-0,01.\dfrac{3}{2}=0,085\left(mol\right)\\ n_{Al_2\left(SO_4\right)_3}=0,01\left(mol\right)\\ CM_{Al_2\left(SO_4\right)_3}=\dfrac{0,01}{0,2}=0,05\left(M\right)\\ CM_{CuSO_4\left(dư\right)}=\dfrac{0,085}{0,2}=0,475M\)
nCuSO4= 0,5.0,2 = 0,1 mol
2Al+3CuSO4→Al2(SO4)3+3Cu
2x……3x……..x……3x (Mol)
Theo bài ta có:
mCu bámvào−mAl tan=mAl tăng
⇔ 3x.64 - 2x.27 = 25,69 - 25
⇔ 138x = 0,69
⇔ x = 0,005 mol
*Tham khảo