a) 2Fe + 6H2SO4 --> Fe2(SO4)3 + 3SO2 + 6H2O
2Fe0-6e-->Fe2+3 | x1 |
S+6 +2e--> S+4 | x3 |
b) \(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\)
\(n_{H_2SO_4}=0,032.2,5=0,08\left(mol\right)\)
PTHH: 2Fe + 6H2SO4 --> Fe2(SO4)3 + 3SO2 + 6H2O
Xét tỉ lệ: \(\dfrac{0,25}{2}>\dfrac{0,08}{6}\) => Al dư, H2SO4 hết
PTHH: 2Fe + 6H2SO4 --> Fe2(SO4)3 + 3SO2 + 6H2O
___________0,08------------------------->0,04
=> VSO2 = 0,04.22,4 = 0,896(l)