\(n_{KClO_3}=\dfrac{a}{122,5}mol\)
\(n_{KMnO_4}=\dfrac{b}{158}mol\)
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
\(\dfrac{a}{122,5}\) \(\dfrac{3a}{245}\)
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
\(\dfrac{b}{158}\) \(\dfrac{b}{316}\)
Sau phản ứng các chất còn lại bằng nhau.
\(\Rightarrow m_{KCl}=m_{K_2MnO_4}+m_{MnO_2}\)
Theo hai pt: \(\dfrac{a}{122,5}\cdot74,5=\dfrac{b}{158}\cdot\left(197+87\right)\)
\(\Rightarrow\dfrac{a}{b}=1,48\)
\(\dfrac{V_{O_2\left(KMnO_4\right)}}{V_{O_2\left(KClO_3\right)}}=\dfrac{\dfrac{b}{316}}{\dfrac{3a}{245}}=\dfrac{245b}{948a}=\dfrac{1}{1,48}\cdot\dfrac{245}{948}=0,17\)