a)
\(n_{KClO_3}=\dfrac{24.5}{122.5}=0.2\left(mol\right)\)
\(2KClO_3\underrightarrow{^{^{t^0}}}2KCl+3O_2\)
\(n_{O_2}=\dfrac{3}{2}\cdot0.2=0.3\left(mol\right)\)
\(V_{O_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(n_{O_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(2KMnO_4\underrightarrow{^{^{t^0}}}K_2MnO_4+MnO_2+O_2\)
\(0.2...............................................0.1\)
\(n_{KMnO_4\left(bđ\right)}=\dfrac{0.2}{90\%}=\dfrac{2}{9}\left(mol\right)\)
\(m_{KMnO_4}=\dfrac{2}{9}\cdot158=35.11\left(g\right)\)
\(n_{Fe_3O_4}=\dfrac{3.48}{232}=0.015\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)
\(0.045....0.03......0.015\)
\(m_{Fe}=0.045\cdot56=2.52\left(g\right)\)
\(V_{O_2}=0.03\cdot22.4=0.672\left(l\right)\)
\(2KClO_3\underrightarrow{^{^{t^0}}}2KCl+3O_2\)
\(0.02......................0.03\)
\(m_{KClO_3}=0.02\cdot122.5=2.45\left(g\right)\)