a) Đặt a=nMg(OH)2 ; b=nFe(OH)3 (a,b>0)
PTHH: Mg(OH)2 -to-> MgO + H2O
a______________a(mol)
2 Fe(OH)3 -to-> Fe2O3 +3 H2O
b_________0,5b(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}58a+107b=165\\40a+80b=165-45=120\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=1\\b=1\end{matrix}\right.\)
=> mMg(OH)=1.58=58(g)
=>%mMg(OH)2= (58/165).100=35,152%
=>%mFe(OH)3= 64,848%
b) PTHH: Fe(OH)3 + 3 HCl -> FeCl3 + 3 H2O
1_______________3(mol)
Mg(OH)2 + 2 HCl -> MgCl2 + H2O
1_______2(mol)
=> mHCl=(2+3).36,5= 182,5(g)
=> mddHCl= (182,5.100)/14,6=1250(g)
=> VddHCl= 1250/1,15= 1086,957(ml)
a) Khối lượng hỗn hợp giảm là khối lượng nước thoát ra
Mg(OH)2 -----to-------> MgO + H2O
x mol ------------------>x------->x (mol)
2Fe(OH)3 ------to----------> Fe2O3 + 3H2O
y mol -----------------------> y/2------->3/2y (mol)
Ta có:\(\left\{{}\begin{matrix}58x+107y=165\\x+\dfrac{3}{2}y=\dfrac{45}{18}=2,5\end{matrix}\right.\)
=> x = 1 và y = 1
=> mMg(OH)2 = 58g và mFe(OH)3 = 107 g
=> %mMg(OH)2 = \(\dfrac{58}{165}.100\) = 35,15%
=> %mFe(OH)3 = 64,85%
b) Y là MgO (1 mol) và Fe2O3 ( 0,5 mol)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
1--------->2 (mol)
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
0,5-------->3 (mol)
=> \(m_{HCl}=\left(2+6\right).36,5=292\left(g\right)\)
=>\(m_{ddHCl}=\dfrac{292}{14,6\%}=2000\left(g\right)\)
=> \(V_{ddHCl}=\dfrac{m}{D}=\dfrac{2000}{1,15}=1739,13\left(ml\right)\)