a, PT: \(4FeS+7O_2\underrightarrow{t^o}2Fe_2O_3+4SO_2\)
\(4FeS_2+11O_2\underrightarrow{t^o}2Fe_2O_3+8SO_2\)
Giả sử: \(\left\{{}\begin{matrix}n_{FeS}=x\left(mol\right)\\n_{FeS_2}=y\left(mol\right)\end{matrix}\right.\)
⇒ 88x + 120y = 17,8 (1)
Ta có: \(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Theo PT: \(n_{SO_2}=n_{FeS}+2n_{FeS_2}=x+2y\left(mol\right)\)
⇒ x + 2y = 0,25 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,075\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{FeS}=0,1.88=8,8\left(g\right)\\m_{FeS_2}=0,075.120=9\left(g\right)\end{matrix}\right.\)
b, Theo PT: \(n_{O_2}=\dfrac{7}{4}n_{FeS}+\dfrac{11}{4}n_{O_2}=0,38125\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,38125.22,4=8,54\left(l\right)\)
Bạn tham khảo nhé!
a) Gọi nFeS = a (mol)
\(n_{FeS_2}=b\left(mol\right)\) với a; b > 0
\(n_{SO_2}=\dfrac{V}{22,4}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Ta có: \(\left\{{}\begin{matrix}m_{hh}=17,8=m_{FeS}+m_{FeS_2}=88a+120b\\n_{S\left(SO_2\right)}=0,25=n_{FeS}+2n_{FeS_2}\left(bt\left[S\right]\right)=a+2b\end{matrix}\right.\)
=> a = 0,1(mol); b = 0,075(mol)
mFeS= n.M= 0,1 . 88 = 8,8(g)
=> \(m_{FeS_2}=m_{hh}-m_{FeS}=17,8-8,8=9\left(g\right)\)
b) PT:
\(4FeS+7O_2\underrightarrow{t^o}2Fe_2O_3+4SO_2\uparrow\\ 4FeS_2+11O_2\underrightarrow{t^o}2Fe_2O_3+8SO_2\uparrow\)
\(Theo2pt\Rightarrow n_{O_2}=\dfrac{7n_{FeS}+11n_{FeS_2}}{4}=0,38125\left(mol\right)\)
\(\Rightarrow V_{O_2}=n\cdot22,4=0,38125\cdot22,4=8,54\left(l\right)\)