\(b,\left(1\right)4Al+3O_2\rightarrow^{t^o}2Al_2O_3\\ \left(2\right)Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\\ \left(3\right)AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\\ \left(4\right)2Al\left(OH\right)_3\rightarrow^{t^o}Al_2O_3+3H_2O\\ \left(5\right)Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
\(a,\left(1\right)Fe+2HCl\rightarrow FeCl_2+H_2\\ \left(2\right)FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl_2\\ \left(3\right)4Fe\left(OH\right)_2+O_2+2H_2O\rightarrow4Fe\left(OH\right)_3\\ \left(4\right)2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\\ \left(5\right)Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)