\(PTHH:Zn+H_2SO_4\to ZnSO_4+H_2\\ CuO+H_2SO_4\to CuSO_4+H_2O\\ \Rightarrow n_{Zn}=n_{H_2}=\dfrac{4,48}{22,4}=0,2(mol)\\ \Rightarrow m_{Zn}=0,2.65=13(g)\\ \Rightarrow \%_{Zn}=\dfrac{13}{21}.100\%=61,9\%\\ \Rightarrow \%_{CuO}=100\%-61,9\%=38,1\%\\ \Rightarrow n_{CuO}=\dfrac{21-13}{80}=0,1(mol)\\ \Rightarrow \Sigma n_{H_2SO_4}=0,1+0,2=0,3(mol)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{0,3}{0,5}=0,6(l)\)