\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,14\left(mol\right)\\n_{HCl}=0,5\left(mol\right)\end{matrix}\right.\)
Gọi công thức chung của 2 axit là HX
=> nHX = 0,14.2 + 0,5 = 0,78 (mol)
Gọi số mol Mg, Al là a, b (mol)
\(n_{H_2}=\dfrac{8,736}{22,4}=0,39\left(mol\right)\)
PTHH: Mg + 2HX --> MgX2 + H2
a---->2a------>a---->a
2Al + 6HX --> 2AlX3 + 3H2
b--->3b------>b----->1,5b
=> \(\left\{{}\begin{matrix}24a+27b=7,74\\a+1,5b=0,39\end{matrix}\right.\)
=> a = 0,12 (mol); b = 0,18 (mol)
=> dd A chứa \(\left\{{}\begin{matrix}MgX_2:0,12\left(mol\right)\\AlX_3:0,18\left(mol\right)\end{matrix}\right.\)
PTHH: MgX2 + 2NaOH --> 2NaX + Mg(OH)2
0,12--->0,24--------------->0,12
AlX3 + 3NaOH --> 3NaX + Al(OH)3
0,18--->0,54--------------->0,18
=> \(V=\dfrac{0,24+0,54}{2}=0,39\left(l\right)\)
mkt = 0,12.58 + 0,18.78 = 21 (g)