\(n_{NO}=a\left(mol\right),n_{N_2O}=b\left(mol\right)\)
\(n_{Al}=\dfrac{4.5}{27}=\dfrac{1}{6}\left(mol\right)\)
Bảo toàn e :
\(3a+8b=\dfrac{1}{6}\cdot3=0.5\left(1\right)\)
\(\overline{M}=16.75\cdot2=33.5\left(g\text{/}mol\right)\)
\(\Rightarrow\dfrac{30a+44b}{a+b}=33.5\)
\(\Rightarrow3.5a-10.5b=0\left(2\right)\)
\(\left(1\right),\left(2\right):a=\dfrac{3}{34},b=\dfrac{1}{34}\)
\(V=\dfrac{3}{34}\cdot22.4=1.98\left(l\right)\)
\(V_1=\dfrac{1}{34}\cdot22.4=0.66\left(l\right)\)