\(a,n_{Na}=\dfrac{4,6}{23}=0,2\left(mol\right)\\ n_{H_2O}=\dfrac{5,4}{18}=0,3\left(mol\right)\)
PTHH: 2Na + 2H2O ---> 2NaOH + H2
LTL: 0,2 < 0,3 => H2O dư
Theo pthh: \(\left\{{}\begin{matrix}n_{H_2}=\dfrac{1}{2}n_{Na}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\n_{NaOH}=n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}b,V_{H_2}=0,1.22,4=2,24\left(l\right)\\m_{NaOH}=0,2.40=8\left(g\right)\end{matrix}\right.\)