BaCl2 + H2SO4 \(\rightarrow\)BaSO4 + 2HCl
nBaCl2=\(\dfrac{31,2}{208}=0,15\left(mol\right)\)
nH2SO4=\(\dfrac{200.9,6\%}{98}=0,2\left(mol\right)\)
VÌ 0,2>0,15 nên H2SO4 dư 0,05 mol
Theo PTHH ta cso:
nBaCl2=nBaSO4=0,15(mol)
2nBaCl2=nHCl=0,3(mol)
mBaSO4=233.0,15=34,95(g)
mHCl=36,5.0,3=10,95(g)
C% dd HCl =\(\dfrac{10,95}{31,2+200-34,95}.100\%=5,58\%\)
C% dd H2SO4=\(\dfrac{0,05.98}{196,25}.100\%=2,5\%\)
BaCl2+H2SO4->BaSO4 +2HCl
a.nBaCl2=\(\dfrac{31,2}{208}=0,15\left(mol\right)\)
nH2SO4=\(\dfrac{200\cdot9,6}{100\cdot98}\approx0,2\left(mol\right)\)
Xét tỉ lệ:\(\dfrac{nBaCl2}{nBaCl2pt}=\dfrac{0,15}{1}< \dfrac{nH2SO4}{nH2SO4pt}=\dfrac{0,2}{1}\)
=>BaCl2 hết, Sản phẩm tính theo H2SO4.
nBaSO4=0,15(mol)=>mBaSO4=0,15*233=34,95(g)
b.dd sau pư gồm: H2SO4 dư và HCl
nH2SO4 dư=0,2-0,15=0,05(mol)=>mH2SO4 dư=0,05*98=4,9(g)
nHCl=0,15*2=0,3(mol)=>mHCl=0,3*36,5=10,95(g)
mdd sau pư=31,2+200-34,95=196,25(g)
C%H2SO4=\(\dfrac{4,9\cdot100}{196,25}=2,497\%\)
C%HCl=\(\dfrac{10,95\cdot100}{196,25}=5,58\%\)