nKOH = 0,2.0,2 = 0,04 (mol)
nH3PO4 = 0,15.0,15 = 0,0225 (mol)
Xét \(\dfrac{n_{KOH}}{n_{H_3PO_4}}=\dfrac{0,04}{0,0225}=1,778\)
=> Tạo ra muối H2PO4- và HPO42-
PTHH: KOH + H3PO4 --> KH2PO4 + H2O
______a---------a-----------------a
2KOH + H3PO4 --> K2HPO4 + 2H2O
_2b----------b--------------b
=> \(\left\{{}\begin{matrix}a+b=0,0225\\a+2b=0,04\end{matrix}\right.=>\left\{{}\begin{matrix}a=0,005\\b=0,0175\end{matrix}\right.\)
\(\left\{{}\begin{matrix}C_{M\left(KH_2PO_4\right)}=\dfrac{0,005}{0,2+0,15}=0,0143M\\C_{M\left(K_2HPO_4\right)}=\dfrac{0,0175}{0,2+0,15}=0,05M\end{matrix}\right.\)