a)
\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(m_{HCl}=\dfrac{175.14,6}{100}=25,55\left(g\right)\\ \rightarrow n_{HCl}=\dfrac{25,55}{35,5}=0,7\left(mol\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
bđ 0,3 0,7
pư 0,3 0,6
spư 0 0,1 0,3 0,3
=> VH2 = 0,3.22,4 = 6,72 (l)
b)
mdd = 16,8 + 175 - 0,3.2 = 191,2 (g)
=> \(\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,3.127}{191,2}.100\%=19,93\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,1.36,5}{191,2}.100\%=1,91\%\end{matrix}\right.\)
\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ n_{HCl}=\dfrac{\dfrac{175.14,6}{100}}{36,5}=0,7\left(mol\right)\\ pthh:Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
\(LTL:\dfrac{0,3}{1}< \dfrac{0,7}{2}\)
\(n_{H_2}=n_{Fe}=0,3\left(mol\right)\\
V_{H_2}=0,3.22,4=6,72\left(l\right)\\
m_{\text{dd}}=16,8+175-\left(0,3.2\right)=191,2\left(g\right)\\
n_{FeCl_2}=n_{Fe}=0,3\left(mol\right)\\
C\%_{FeCl_2}=\dfrac{0,3.127}{191,2}.100\%=19,92\%\)
=> HCl dư