\(a,Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right);n_{HCl}=2.0,2=0,4\left(mol\right)\\ m_{ZnCl_2}=136.0,2=27,2\left(g\right);C_{MddHCl}=\dfrac{0,4}{0,1}=4\left(M\right)\\ b,Zn+CuSO_4\rightarrow ZnSO_4+Cu\\ n_{CuSO_4}=\dfrac{20.10\%}{160}=0,0125\left(mol\right);n_{Zn}=0,2\left(mol\right)\\ Vì:\dfrac{0,0125}{1}< \dfrac{0,2}{1}\Rightarrow Zn.dư\\ n_{Zn\left(p.ứ\right)}=n_{ZnSO_4}=n_{CuSO_4}=0,0125\left(mol\right)\\m_{Zn\left(p.ứ\right)}=0,0125.65=0,8125\left(g\right)\\ m_{ddsau}=m_{Zn\left(p.ứ\right)}+m_{ddCuSO_4}=0,8125+20=20,8125\left(g\right)\\ C\%_{ddZnSO_4}=\dfrac{0,0125.161}{20,8125}.100\approx9,67\%\)