a) Gọi $n_{Zn} = a(mol) ; n_{Al} = b(mol) \Rightarrow 65a + 27b = 21,1(1)$
$Zn + 2HCl \to ZnCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH :
$n_{HCl} = 2a + 3b = 0,65.2 = 1,3(2)$
Từ (1)(2) suy ra : a = 0,2 ; b = 0,3
$\%m_{Zn} = \dfrac{0,2.65}{21,1}.100\% = 61,6\%$
$\%m_{Al} = 100\% - 61,6\% = 38,4\%$
b) $n_{ZnCl_2} = 0,2(mol) ; n_{AlCl_3} = 0,3(mol)$
Suy ra :
$m_{ZnCl_2} = 0,2.136 = 27,2(gam)$
$m_{AlCl_3} = 0,3.133,5 = 40,05(gam)$