a)
$n_{HCl} = \dfrac{3,65}{36,5} = 0,1(mol)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{CaCO_3} = n_{CaCl_2} = n_{CO_2} = \dfrac{1}{2}n_{HCl} = 0,05(mol)$
$\%m_{CaCO_3} = \dfrac{0,05.100]{31,1}.100\% = 16,08\%$
$\%m_{Ba(NO_3)_2} = 100\% -16,08\% = 83,92\%$
b)
$m_{dd\ sau\ pư} = 31,1 + 96,1 - 0,05.44 = 125(gam)$
$C\%_{Ba(NO_3)_2} = \dfrac{31,1 - 0,05.100}{125}.100\% = 20,88\%$
$C\%_{CaCl_2} = \dfrac{0,05.111}{125}.100\% = 4,44\%$