Câu 5
Gọi khối lượng dd H2SO4 85% là a (g)
Gọi khối lượng dd HNO3 x% là b (g)
\(m_{H_2SO_4}=\dfrac{85a}{100}=0,85a\left(g\right)\)
\(m_{HNO_3}=\dfrac{bx}{100}=0,01bx\left(g\right)\)
mdd sau pư = a + b (g)
\(C\%_{H_2SO_4}=\dfrac{0,85a}{a+b}.100\%=60\%\)
=> \(\dfrac{a}{b}=\dfrac{12}{5}\)
\(C\%_{HNO_3}=\dfrac{0,01bx}{a+b}.100\%=\dfrac{0,01bx}{\dfrac{12}{5}b+b}.100\%=\dfrac{0,01x}{3,4}.100\%=20\%\)
=> x = 68
Câu 6:
1)
CTHH oxit cao nhất là RO2
\(\%O=\dfrac{32}{M_R+32}.100\%=53,33\%\)
=> MR = 28 (g/mol)
=> R là Silic (Si)
2)
\(n_{H_2\left(1\right)}=\dfrac{1,344}{22,4}=0,06\left(mol\right)\)
PTHH: MxOy + yH2 --to--> xM + yH2O (1)
\(\dfrac{0,06}{y}\)<--0,06-->\(\dfrac{0,06x}{y}\)
=> \(M_{M_xO_y}=x.M_M+16y=\dfrac{3,48}{\dfrac{0,06}{y}}=56y\left(g/mol\right)\)
=> x.MM = 42y
=> \(\dfrac{x}{y}=\dfrac{42}{M_M}\) (*)
\(n_{H_2\left(2\right)}=\dfrac{1,008}{22,4}=0,045\left(mol\right)\)
PTHH: 2M + 2nHCl --> 2MCln + nH2
\(\dfrac{0,09}{n}\)<--------------------0,045
=> \(\dfrac{0,06x}{y}=\dfrac{0,09}{n}\) (**)
(*)(**) => \(\dfrac{2,52}{M_M}=\dfrac{0,09}{n}\)
=> MM = 28n (g/mol)
- Nếu n = 1 => Loại
- Nếu n = 2 => MM = 56 (g/mol) --> Fe
- Nếu n = 3 => MM = 84 (Loại)
Vậy M là Fe
\(\dfrac{x}{y}=\dfrac{42}{56}=\dfrac{3}{4}\) => CTHH: Fe3O4