This is the chemical formula for the hydroperoxyl radical.It is a very important molecule in atmospheric and combustion chemistry.
The hydroperoxyl radical is an extremely reactive chemical species.
In the atmosphere (specifically the troposphere), HO2⋅ plays a central role in complex photochemical cycles that govern air quality. It acts as an oxidizing agent and a chain-carrier for reactions.
Key Reactions | ||
Ozone (O3) Formation | In polluted environments (high NOx ), HO2⋅ converts nitric oxide ( NO ) into nitrogen dioxide ( NO2 ), which then photolyzes to produce ground-level ozone, a major component of smog. | HO2⋅+NO→OH⋅+NO2 |
Recycling the Hydroxyl Radical | This reaction with NO regenerates the highly reactive hydroxyl radical ( OH⋅ ), sustaining the atmospheric oxidation chain. | HO2⋅+NO→OH⋅+NO2 |
Hydrogen Peroxide (H2O2) Source | The self-reaction (or termination reaction) of two HO2⋅ radicals is the main source of hydrogen peroxide ( H2O2 ) in the gas phase. H2O2 is then important for liquid-phase chemistry in clouds. | HO2⋅+HO2⋅→H2O2+O2 |
Oxidation of Organics | HO2⋅ (and its organic version, RO2⋅ ) react with and degrade organic pollutants (Volatile Organic Compounds or $\text{VOC}$s), acting as an atmospheric "cleanser." | RO2⋅+HO2⋅→ROOH+O2 |
In living systems, theHO2⋅/O2−⋅ pair is an essential Reactive Oxygen Species (ROS) involved in cellular signaling, defense, and damage.
"ho2" thường dùng để chỉ gốc tự do hydroperoxyl (hoặc hydro superoxide), có công thức hóa học là HO₂. Đây là một dạng ion của superoxide được proton hóa, có vai trò quan trọng trong các quá trình hóa học ở khí quyển và sinh học tế bào.