\(M_{CaCO_3}=40+12+16.3=100\left(\dfrac{g}{mol}\right)\\ \%m_{Ca}=\dfrac{40}{100}.100\%=40\%\\ \%m_C=\dfrac{12}{100}.100\%=12\%\\ \%m_O=100\%-\left(12\%+40\%\right)=48\%\\ M_{Al_2\left(SO_4\right)_3}=27.2+\left(32+16.4\right).3=342\left(\dfrac{g}{mol}\right)\\ \%m_{Al}=\dfrac{2.27}{342}.100\%=15,79\%\\ \%m_S=\dfrac{32.3}{342}.100\%=28\%\\ \%m_O=100\%-\left(28\%+15,79\%\right)=56,21\%\)