MgO + 2HCl \(\rightarrow\)MgCl2 + H2O
nMgO=\(\dfrac{6,8}{40}=0,17\left(mol\right)\)
mHCl=\(100.\dfrac{14,6}{100}=14,6\left(g\right)\)
nHCl=\(\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
Vậy HCl dư 0,06 mol,sản phẩm dc tính theo MgO
Theo PTHH ta có:
nMgO=nMgCl2=0,17(mol)
mMgCl2=95.0,17=16,15(g)
mHCl(còn dư)=0,06.36,5=2,19(g)
C%dd MgCl2=\(\dfrac{16,15}{6,8+100}.100\%=15,12\%\)
C% dd HCl=\(\dfrac{2,19}{6,8+100}.100\%=2\%\)
PTHH: MgO + 2HCl ----> MgCl2 + H2O
nMgO = \(\dfrac{6,8}{40}=0,17\left(mol\right)\)
mHCl = \(\dfrac{14,6\%.100}{100}=14,6\left(g\right)\)
nHCl = \(\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
Ta có tỉ lệ: \(\dfrac{0,17}{1}< \dfrac{0,4}{2}\) => MgO phản ứng hết, HCl dư
Theo PTHH: nHCl(p/ứ) = 2nMgO = 0,34 (mol)
=> nHCl(dư) = 0,4 - 0,34 = 0,06 (mol)
=> mHCl(dư) = 0,06.36,5 = 2,19 (g)
Theo PTHH: n\(MgCl_2\) = nMgO = 0,17 (mol)
=> mMgCl2 = 0,17.95 = 16,15 (g)
m\(ddspu\) = 6,8+100 = 106,8 (g)
C%HCl = \(\dfrac{2,19}{106,8}.100\%=2,05\%\)
C%\(MgCl_2\) = \(\dfrac{16,15}{106,8}.100\%=15,12\%\)