\(\text{nCO2= 4,48:22,4=0,2 mol}\)
MgO + 2HCl -> MgCl2+ H2O
MgCO3 +2 HCl -> MgCl2+ H2O + CO2
mol 0,2....<- 0,4.....<-0,2 .................<-0,2
\(\Rightarrow\text{ mMgCO3=0,2.84=16,8(g) }\)
\(\Rightarrow\text{mMgO=20,8-16,8=4g}\)
\(\Rightarrow\text{%MgCO3= 16,8:20,8.100%=80,77%}\)
\(\Rightarrow\text{ %MgO=100-80,77=19,23%}\)
\(\text{b, nMgO=4÷ 0,1(mol)}\)
Theo PTHH 1: n HCl= 2n MgO= 0,1.2= 0,2
\(\text{nHCl = 2nMgCO3= 0,2.2= 0,4}\)
\(\Rightarrow\text{nHCl=0,2+0,4=0,6}\)
\(\Rightarrow\text{mHCl=0,6. 36,5=21,9g}\)
\(\Rightarrow\text{mddHCl= 21,9.100:7,3=300g}\)
\(\Rightarrow\text{ V= 300: 1,05=285,71g}\)
MgO+2HCl---->MgCl2+H2
MgCO3+2HCl--->MgCl2+H2O+CO2
n\(_{CO2}=\frac{4,48}{22,4}=0,2\left(mol\right)\)
Theo pthh2
n\(_{MgCO3}=n_{CO2}=0,2\left(mol\right)\)
%m MgCO3=\(\frac{0,2.84}{20,8}.100\%=80,77\%\)
%m MgO=100-80,77=19,23%
b) mol HCl ở PT1 là n\(_{HCl}=2n_{MgO}=\frac{4}{40}.2=0,2\left(mol\right)\)
mol HCl ở pt2 là n\(_{HCl}=2n_{CO2}=0,4\left(mol\right)\)
Tổng mol HCl =0,2+0,4=0,6(mol)
m\(_{ddHCl}=\frac{0,6.36,5.100}{7,3}=300\left(g\right)\)
V HCl=300/1,05=285,71(l)
c) Theo pthh1
n\(_{MgCl2}=n_{MgO}=0,1\left(mol\right)\)
m dd sau pư=300+20,8-8,8=312(g)
Theo pthh2
n\(_{MgCl2}=n_{CO2}=0,2\left(mol\right)\)
C% MgCl2 =\(\frac{0,3.95}{312}.100\%=9,13\%\)