a)+b)
\(m_{H_2SO_4}\)=100.20%=20g
=>\(n_{H_2SO_4}\)=20:98=0,2(mol)
nCuO=1,6:80=0,02(mol)
CuO+H2SO4->CuSO4+H2O
0,02......0,02.........0,02.............(mol)
Ta có:\(\dfrac{n_{CuO}}{1}< \dfrac{n_{H_2SO_4}}{1}\)=>CuO hết,H2SO4 dư
Theo PTHH:\(m_{CuSO_4}\)=0,02.160=3,2(g)
\(n_{H_2SO_4\left(dư\right)}\)=0,2-0,02=0,18(mol)
=>\(m_{H_2SO_4\left(dư\right)}\)=0,18.98=17,64(g)
mdd(sau)=1,6+100=101,6(g)
Vậy \(C_{\%CuSO_4}\)=\(\dfrac{3,2}{101,6}\).100%=3,15%
\(C_{\%H_2SO_4\left(dư\right)}\)=\(\dfrac{17,64}{101,6}\).100%=17,4%
Theo đề bài ta có :\(\left\{{}\begin{matrix}nCuO=\dfrac{1,6}{80}=0,02\left(mol\right)\\nH2SO4=\dfrac{100.20}{100.98}\approx0,2\left(mol\right)\end{matrix}\right.\)
a) Ta có PTHH :
CuO + H2SO4 \(\rightarrow\) CuSO4 + H2O
0,02mol...0,02mol....0,02mol
Theo PTHH ta có : \(\dfrac{0,02}{1}mol< nH2SO4=\dfrac{0,2}{1}mol\)
=> nH2SO4 dư ( tính theo nCuO )
b) Sau P/Ư thu được dung dịch CuSO4 và H2SO4 dư
C% \(_{C\text{uS}O4}=\dfrac{0,02.160}{1,6+100}.100\%\approx3,15\%\)
C%\(_{H2SO4\left(d\text{ư}\right)}=\dfrac{\left(0,2-0,02\right).98}{1,6+100}.100\%\approx17,36\%\)
nCuO = \(\dfrac{1,6}{80}=0,02\left(mol\right)\) và: n\(H_2SO_4\)=\(\dfrac{100.20}{100.98}\simeq0,204\left(mol\right)\)
a) PTHH:
CuO + H2SO4 ----> CuSO4 + H2O
0,02......0,204 (mol)
Tỉ lệ: \(\dfrac{0,02}{1}< \dfrac{0,204}{1}\Rightarrow H_2SO_4dư\)
b)
Có: n\(H_2SO_4\) (pu) = nCuO =0,02 (mol)
=> m\(H_2SO_4\) (dư) = (0,204 - 0,02 ) . 98 = 18,032 (g)
và: n\(H_2SO_4\) = nCuO = 0,02 (mol)
=> mCuSO4 = 0,02.160=3,2(gam)
Suy ra:
C% H2SO4 (dư) = \(\dfrac{18,032}{101,6}.100\%\simeq17,75\%\)
C% CuSO4 = \(\dfrac{3,2}{101,6}.100\%\simeq3,15\%\)