\(n_{C\left(1\right)}=n_{CaCO_3\left(1\right)}=\dfrac{20}{100}=0,02\left(mol\right)\)
\(n_{C\left(2\right)}=n_{HCO_3^-}=2n_{CaCO_3\left(2\right)}=2.\dfrac{10}{100}=0,2\left(mol\right)\)
\(\Rightarrow\Sigma n_C=0,22\left(mol\right)\)
\(\Rightarrow V_{CO_2}=4,928\left(l\right)\)