nH2= 0,15(mol)
mHCl= 146.20%=29,2(g) => nHCl=0,8(mol)
a) PTHH: Mg + 2 HCl -> MgCl2 + H2
x____________2x____x_______x(mol)
Fe +2 HCl -> FeCl2 + H2
y____2y____y_____y(mol)
Vì nH2< nHCl/2 -> HCl dư
Ta có hpt:
\(\left\{{}\begin{matrix}24x+56y=6,8\\x+y=0,15\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,05\\y=0,1\end{matrix}\right.\)
=> mMg=0,05.24=1,2(g)
=>%mMg=(1,2/6,8).100=17,647%
=>%mFe=82,353%
b) mddY= 6,8+ 146 - (2x+2y)= 6,8+146 - (2.0,05+2.0,1)= 152,5(g)
mFeCl2=0,1.127=12,7(g)
mMgCl2=0,05.95= 4,75(g)
mHCl(dư)= 29,2 - (2x+2y).36,5= 18,25(g)
=>C%ddFeCl2= (12,7/152,5).100=8,328%
C%ddHCl(dư)= (18,25/152,5).100=11,967%
C%ddMgCl2= (4,75/152,5).100=3,115%