a, PTHH:
(1) 2Na + 2H2O→ 2NaOH + H2
2mol 2mol 2mol 1mol
(2) Na2O + H2O → 2NaOH
1mol 1mol 2mol
b,
-Tính nH2
nH2= \(\dfrac{3.36}{22.4}\)=0.15 → mH2= 0.15*2=0.3(g)
-Theo PT(1) ta có
nNa=nNaOH(1)=2nH2= 2*0.15=0.3(mol)
→mNa= 0.3*23= 6.9(g)
mNaOH(1)= 0.3*40=12(g)
-Tính mNa2O
mNa2O= 13.1-6.9= 6.2(g)
→nNa2O= \(\dfrac{6.2}{62}\)=0.1(mol)
-Theo PT(2) ta có
nNaOH(2)=2Na2O=2*0.1=0.2(mol)
→mNaOH(2)=0.2*23=4.6(g)
-Tính mNaOH
mNaOH= mNaOH(1)+mNaOH(2)=12+4.6=16.6(g)
-Tính C%
C%= \(\dfrac{16.6}{100+13.1-0.3}\)*100%≃ 14.7%
c,
PTHH3:CO2 +2NaOH → Na2CO3 + H2O
1mol 2mol 1mol 1mol
-Theo Đb ta có:
mNaOH(3) = 1/2mNaOH(1)+(2)= \(\dfrac{16.6}{2}\)= 8.3(g)
→nNaOH(3)= \(\dfrac{8.3}{40}\)= 0.2075(mol)
-TheoPT(3) ta có
nNa2CO3=1/2nNaOH(3)= \(\dfrac{0.2075}{2}\)=0.10375(mol)
→mNa2CO3=0.10375*106≃11(g)
-Tính C%
C%=\(\dfrac{11}{11+1.8675}\)*100%≃ 85.4867%