a)
Gọi số mol Fe, Fe2O3 là a, b (mol)
=> 56a + 160b = 48,8 (1)
PTHH: 2Fe + 6H2SO4 --> Fe2(SO4)3 + 3SO2 + 6H2O
a-------------------->0,5a------>1,5a
Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
b----------------------->b
=> \(0,5a+b=\dfrac{140}{400}=0,35\) (2)
(1)(2) => a = 0,3 (mol); b = 0,2 (mol)
=> \(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,3.56}{48,8}.100\%=34,426\%\\\%m_{Fe_2O_3}=\dfrac{0,2.160}{48,8}.100\%=65,574\%\end{matrix}\right.\)
b) nSO2 = 1,5a = 0,45 (mol)
nNaOH = 1.0,45 (mol)
Xét tỉ lệ: \(\dfrac{n_{NaOH}}{n_{SO_2}}=\dfrac{0,45}{0,45}=1\) => Tạo muối NaHSO3
PTHH: NaOH + SO2 --> NaHSO3
0,45-------------->0,45
=> \(C_{M\left(dd.NaHSO_3\right)}=\dfrac{0,45}{0,45}=1M\)
