\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\)
\(n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\)
a) 4P + 5O2 \(\underrightarrow{to}\) 2P2O5 (1)
b) Theo PT1: \(n_P=\dfrac{4}{5}n_{O_2}\)
theo bài: \(n_P=n_{O_2}\)
Vì \(1>\dfrac{4}{5}\) ⇒ P dư
Theo PT1: \(n_Ppư=\dfrac{4}{5}n_{O_2}=\dfrac{4}{5}\times0,4=0,32\left(mol\right)\)
\(\Rightarrow n_Pdư=0,4-0,32=0,08\left(mol\right)\)
\(\Rightarrow m_Pdư=0,08\times31=2,48\left(g\right)\)
c) Theo PT1: \(n_{P_2O_5}=\dfrac{2}{5}n_{O_2}=\dfrac{2}{5}\times0,4=0,16\left(mol\right)\)
\(\Rightarrow m_{P_2O_5}=0,16\times142=22,72\left(g\right)\)
\(\Rightarrow m_{sp}=m_Pdư+m_{P_2O_5}=2,48+22,72=25,2\left(g\right)\)
d) 2KMnO4 \(\underrightarrow{to}\) K2MnO4 + MnO2 + O2 (2)
Theo PT2: \(n_{KMnO_4}=2n_{O_2}=2\times0,4=0,8\left(mol\right)\)
\(\Rightarrow m_{KMnO_4}=0,8\times158=126,4\left(g\right)\)
\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\)
\(n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\)
a. PTHH: \(4P+5O_2-t^o->2P_2O_5\)
Theo PTHH và đề bài ta có tỉ lệ:
\(\dfrac{0,4}{4}=0,1>\dfrac{0,4}{5}=0,08\)
b. => P dư. \(O_2\) hết => tính theo \(n_{O_2}\)
Theo PT ta có: \(n_{P\left(pư\right)}=\dfrac{0,4.4}{5}=0,32\left(mol\right)\)
=> \(n_{P\left(dư\right)}=0,4-0,32=0,08\left(mol\right)\)
=> \(m_{P\left(dư\right)}=0,08.31=2,48\left(g\right)\)
c. Theo PT ta có: \(n_{P2O5}=\dfrac{0,4.2}{5}=0,16\left(mol\right)\)
=> \(m_{P2O5}=0,16.142=22,72\left(g\right)\)
=> \(m_{sảnphẩmthuđược}=m_{P\left(dư\right)}+m_{P_2O_5}=2,48+22,72=25,2\left(g\right)\)
d. PTHH: \(2KMnO_4-t^o->K_2MnO_4+MnO_2+O_2\uparrow\)
Ta có: \(n_{O_2}=0,4\left(mol\right)\)
Theo PT ta có: \(n_{KMnO_4}=\dfrac{0,4.2}{1}=0,8\left(mol\right)\)
=> \(m_{KMnO_4\left(cầndùng\right)}=0,8.158=126,4\left(g\right)\)