PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
a, Giả sử: \(\left\{{}\begin{matrix}n_{Fe}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\)
Ta có: \(m_{H_2SO_4}=\frac{196.20}{100}=39,2\left(g\right)\Rightarrow n_{H_2SO_4}=\frac{39,2}{98}=0,4\left(mol\right)\)
Theo PT: \(\Sigma n_{H_2SO_4}=x+3y=0,4\left(1\right)\)
Ta có: \(n_{H_2}=\frac{0,4}{2}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,2\left(mol\right)\Rightarrow x=0,2\left(2\right)\)
Từ (1) và (2) ⇒ x = 0,2 (mol) ; y = 1/15 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\frac{0,2.56}{0,2.56+\frac{1}{15}.160}.100\%\approx51,2\%\text{ }\\\%m_{Fe_2O_3}\approx48,8\%\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{FeSO_4}=n_{Fe}=0,2\left(mol\right)\\n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=\frac{1}{15}\left(mol\right)\end{matrix}\right.\)
Ta có: m dd sau pư = mFe + mFe2O3 + m dd H2SO4 - mH2
= 0,2.56 + 1/15.160 + 196 - 0,4
≃ 217,467 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeSO_4}=\frac{0,2.152}{217,467}.100\%\approx13,98\%\\C\%_{Fe_2\left(SO_4\right)_3}=\frac{\frac{1}{15}.400}{217,467}.100\%\approx12,26\%\end{matrix}\right.\)
Bạn tham khảo nhé!
PT: Fe+H2SO4→FeSO4+H2Fe+H2SO4→FeSO4+H2
Fe2O3+3H2SO4→Fe2(SO4)3+3H2OFe2O3+3H2SO4→Fe2(SO4)3+3H2O
a, Giả sử: {nFe=x(mol)nFe2O3=y(mol){nFe=x(mol)nFe2O3=y(mol)
Ta có: mH2SO4=196.20100=39,2(g)⇒nH2SO4=39,298=0,4(mol)mH2SO4=196.20100=39,2(g)⇒nH2SO4=39,298=0,4(mol)
Theo PT: ΣnH2SO4=x+3y=0,4(1)ΣnH2SO4=x+3y=0,4(1)
Ta có: nH2=0,42=0,2(mol)nH2=0,42=0,2(mol)
Theo PT: nFe=nH2=0,2(mol)⇒x=0,2(2)nFe=nH2=0,2(mol)⇒x=0,2(2)
Từ (1) và (2) ⇒ x = 0,2 (mol) ; y = 1/15 (mol)
⇒⎧⎨⎩%mFe=0,2.560,2.56+115.160.100%≈51,2% %mFe2O3≈48,8%⇒{%mFe=0,2.560,2.56+115.160.100%≈51,2% %mFe2O3≈48,8%
b, Theo PT: {nFeSO4=nFe=0,2(mol)nFe2(SO4)3=nFe2O3=115(mol){nFeSO4=nFe=0,2(mol)nFe2(SO4)3=nFe2O3=115(mol)
Ta có: m dd sau pư = mFe + mFe2O3 + m dd H2SO4 - mH2
= 0,2.56 + 1/15.160 + 196 - 0,4
≃ 217,467 (g)
⇒⎧⎪⎨⎪⎩C%FeSO4=0,2.152217,467.100%≈13,98%C%Fe2(SO4)3=115.400217,467.100%≈12,26%